Journal
ACS APPLIED MATERIALS & INTERFACES
Volume 6, Issue 21, Pages 18538-18542Publisher
AMER CHEMICAL SOC
DOI: 10.1021/am5057147
Keywords
supramolecular chemistry; amphiphilie; self-assembly; magnetic-responsive; host-guest interaction
Funding
- National Natural Science Foundation of China [21273195]
- Priority Academic Program Development of Jiangsu Higher Education Institutions
- Qing Lan Project of Jiangsu Province
- Jiangsu Key Laboratory of Environmental Material and Environmental Engineering [K13062]
- [BK2013016]
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A new amphiphilic pillar[5]arene (AP5-glycol) with five oligomeric glycol groups and five alkyl chains was prepared. AP5-glycol spontaneously formed bilayer vesicles in water, and these vesicles were still stable after several weeks. Additionally, when they were exposed to external physical stimuli, these vesicles also showed reversible thermal and dynamic properties. Interestingly, oleic-acid-stabilized magnetic iron oxide nanoparticles could be incorporated into the bilayer of the AP5-glycol vesicles to form hybrid magnetic-responsive supramolecular vesicles.
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