4.8 Article

Tuning the Resonant Frequency of Resonators Using Molecular Surface Self-assembly Approach

Journal

ACS APPLIED MATERIALS & INTERFACES
Volume 7, Issue 1, Pages 950-958

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/am507640g

Keywords

film bulk acoustic resonator (FBAR); frequency tuning; gas sensor; layer-by-layer (LbL) self-assembly; resonators

Funding

  1. Natural Science Foundation of China (NSFC) [61176106]
  2. 111 Project [B07014]
  3. Tianjin Applied Basic Research and Advanced Technology [14JCYBJC41500]

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In this work, a new method to tune the resonant frequency of microfabricated resonator using molecular layer-by-layer (LbL) self-assembly approach is demonstrated. By simply controlling the polymer concentration and the number of layers deposited, precisely tuning the frequency of microfabricated resonators is realized. Due to its selective deposition through specific molecular recognitions, such technique avoids the high-cost and complex steps of conventional semiconductor fabrications and is able to tune individual diced device. Briefly, film bulk acoustic resonator (FBAR) is used to demonstrate the tuning process and two types of LbL deposition methods are compared. The film thickness and morphology have been characterized by UV-vis reflection spectra, ellipsometer and AFM. As a result, the maximum resonant frequency shift of FBAR reaches more than 20 MHz, meaning 1.4% tunability at least. The minimum frequency shift is nearly 10 kHZ per bilayer, indicating 7 ppm tuning resolution. Pressure cooker test (PCT) is performed to evaluate the reliability of LbL coated FBAR. Furthermore, applications for wireless broadband communication and chemical sensors of LbL coated FBAR have been demonstrated.

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