Journal
ACS APPLIED MATERIALS & INTERFACES
Volume 6, Issue 17, Pages 15040-15051Publisher
AMER CHEMICAL SOC
DOI: 10.1021/am503038t
Keywords
boron; germanium; silicon; phthalocyanine; ternary; cascade; builk; heterojunction; solar; cell; photovoltaic; P3HT; PC6BM
Funding
- Saudi Basic Industries (SABIC)
- Natural Sciences and Engineering Research Council (NSERC) of Canada
- government of Canada
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Previous studies have shown that the use of bis(tri-n-hexylsilyl oxide) silicon phthalocyanine ((3HS)(2)-SiPc) as an additive in a P3HT:PC61BM cascade ternary bulk heterojunction organic photovoltaic (BHJ OPV) device results in an increase in the short circuit current (JSC) and efficiency (eta(eff)) of up to 25% and 20%, respectively. The previous studies have attributed the increase in performance to the presence of (3HS)(2)-SiPc at the BHJ interface. In this study, we explored the molecular characteristics of (3HS)(2)-SiPc which makes it so effective in increasing the OPV device JSC and eta(eff). Initially, we synthesized phthalocyanine-based additives using different core elements such as germanium and boron instead of silicon, each having similar frontier orbital energies compared to (3HS)(2)-SiPc and tested their effect on BHJ OPV device performance. We observed that addition of bis(tri-n-hexylsilyl oxide) germanium phthalocyanine ((3HS)2-GePc) or tri-n-hexylsilyl oxide boron subphthalocyanine (3HS-BsubPc) resulted in a nonstatistically significant increase in JSC and eta(eff). Secondly, we kept the silicon phthalocyanine core and substituted the tri-n-hexylsilyl solubilizing groups with pentadecyl phenoxy groups and tested the resulting dye in a BHJ OPV. While an increase in JSC and eta(eff) was observed at low (PDP)2-SiPc loadings, the increase was not as significant as (3HS)(2)-SiPc; therefore, (3HS)2-SiPc is a unique additive. During our study, we observed that (3HS)(2)-SiPc had an extraordinary tendency to crystallize compared to the other compounds in this study and our general experience. On the basis of this observation, we have offered a hypothesis that when (3HS)(2)-SiPc migrates to the P3HT:PC61BM interface the reason for its unique performance is not solely due to its frontier orbital energies but also might be due to a high driving force for crystallization.
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