4.8 Article

Designed Synthesis of SiO2/TiO2 Core/Shell Structure As Light Scattering Material for Highly Efficient Dye-Sensitized Solar Cells

Journal

ACS APPLIED MATERIALS & INTERFACES
Volume 5, Issue 11, Pages 4815-4820

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/am400441v

Keywords

SiO2/TiO2 core/shell nanoparticle; light scattering; Mie scattering; dye-sensitized solar cell

Funding

  1. Global Frontier R&D Program on Center for Multiscale Energy System
  2. National Research Foundation under the Ministry of Education, Science and Technology, Korea [2011-0031573]
  3. WCU (World Class University) program through the National Research Foundation of Korea
  4. Ministry of Education, Science and Technology [R31-10013]
  5. National Research Foundation of Korea [R31-2012-000-10013-0, 2011-0031573] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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SiO2/TiO2 core/shell nanoparticles (STCS-NPs) with diameters of 110, 240, and 530 nm were fabricated to investigate the influence of the size and refractive index of light-scattering particles on light-scattering properties. The optical properties of STCS-NPs were evaluated and compared with SiO2-NPs and TiO2-NPs. The structure of STCS-NPs, consisting of a low refractive index core and high refractive index shell, provides efficient light scattering. The optimized anode film with STCS-NPs had ca. 20% improved power conversion efficiency (PCE).

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