4.8 Article

Reduced Graphene Oxide Wrapped FeS Nanocomposite for Lithium-Ion Battery Anode with Improved Performance

Journal

ACS APPLIED MATERIALS & INTERFACES
Volume 5, Issue 11, Pages 5330-5335

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/am401239f

Keywords

FeS; reduced graphene oxide; nanocomposite; lithium-ion battery

Funding

  1. NSF [1131290]
  2. Graduate School at NMSU
  3. Directorate For Engineering
  4. Div Of Civil, Mechanical, & Manufact Inn [1131290] Funding Source: National Science Foundation

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A new nanocomposite formulation of the FeS-based anode for lithium-ion batteries is proposed, where FeS nanoparticles wrapped in reduced graphene oxide (RGO) are produced via a facile direct-precipitation approach. The resulting nanocomposite FeS@RGO structure has better lithium ion storage properties, exceeding those of FeS prepared without RGO sheets. The enhanced electrochemical performance is attributed to the robust sheet-wrapped structure with smaller FeS nanoparticles and synergetic effects between FeS and RGO sheets, such as increased conductivity, shortened lithium ion diffusion path, and the effective prevention of polysulfide dissolution.

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