4.8 Article

Polyvinyl Alcohol-Cellulose Nanofibrils-Graphene Oxide Hybrid Organic Aerogels

Journal

ACS APPLIED MATERIALS & INTERFACES
Volume 5, Issue 13, Pages 5969-5975

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/am400171y

Keywords

organic aerogels; cellulose nanofibrils; graphene oxide; nanocomposites; thermal conductivity; hydrophobicity

Funding

  1. National Science Foundation [CMMI 1032186]
  2. USDA Forest Products Laboratory (Madison, WI)

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Hybrid organic aerogels consisting of polyvinyl alcohol (PVA), cellulose nanofibrils (CNFs), and graphene oxide nanosheets (GONSs) were prepared using an environmentally friendly freeze-drying process. The material properties of these fabricated aerogels were measured and analyzed using various characterization techniques including, compression testing, scanning electron microscopy, thermogravimetric (TGA) analysis, Bninatier-Emmet-Teller (BET) surface area analysis, and contact angle measurements. These environmentally friendly,. biobased hybrid organic aerogels exhibited a series of desirable properties including a high specific compressive strength and compressive failure strain, ultralow density and thermal conductivity, good thermal stability, and moisture resistance, making them potentially useful for a broad range of applications including thermal insulation.

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