4.8 Article

Preparation and Photocatalytic Activity of Robust Titania Monoliths for Water Remediation

Journal

ACS APPLIED MATERIALS & INTERFACES
Volume 5, Issue 3, Pages 500-504

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/am302654r

Keywords

titania; monolith; photocatalysis; water remediation

Funding

  1. Ministry of Education, Culture, Sports, Science and Technology of Japan
  2. Japan Society for the Promotion of Science (JSPS)
  3. Grants-in-Aid for Scientific Research [12F02345] Funding Source: KAKEN

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TiO2 monoliths were prepared, characterized, and evaluated for photocatalytic performance. The TiO2 monoliths were found to have an interconnected void lattice and a bimodal porous structure with macropores and mesopores after calcination at 500-700 degrees C. Monoliths calcined at 500 degrees C had high specific surface area (93.1 m(2)/g) and porosity (68%), which were maintained after calcination at 700-1100 degrees C (51-46%). The calcined monoliths had relatively high Vickers hardness (similar to 104) despite their porous structure. Monoliths calcined at 500 and 700 degrees C exhibited high performance because of their high specific surface area.

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