Journal
ACS APPLIED MATERIALS & INTERFACES
Volume 5, Issue 21, Pages 10836-10841Publisher
AMER CHEMICAL SOC
DOI: 10.1021/am403039u
Keywords
chromatic transition; sensors; polydiacetylene; energy transfer; tetrazine
Funding
- DGA (Direction Generale de l'Armement)
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A new reactive diacetylene molecule has been synthesized, incorporating a strongly luminescent chromophore, tetrazine (Tz). It readily polymerizes into the blue polydiacetylene (PDA) form, quenching the Tz luminescence already at concentrations <= 1 %. The blue to red PDA transition is thermally induced in the solid state and the original strong Tz emission is restored. This might lead to a new type of detection for sensors using the PDA color transition.
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