4.8 Article

Highly Transparent Carbon Counter Electrode Prepared via an in Situ Carbonization Method for Bifacial Dye-Sensitized Solar Cells

Journal

ACS APPLIED MATERIALS & INTERFACES
Volume 5, Issue 15, Pages 7432-7438

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/am4017472

Keywords

in situ carbonization method; transparent carbon counter electrode; optical and electrochemical properties; bifacial dye-sensitized solar cells; long-term stability

Funding

  1. National Basic Research Program of China [2011CB933300]
  2. National Science Fund for Talent Training in Basic Science [J1210061]
  3. National Natural Science Foundation of China [51132001, 51272184]

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A facile in situ carbonization method was demonstrated to prepare the highly transparent carbon counter electrode (CE) with good mechanical stability for bifacial dye-sensitized solar cells (DSCs). The optical and electrochemical properties of carbon CEs were dramatically affected by the composition and concentration of the precursor. The well-optimized carbon CE exhibited high transparency and sufficient catalytic activity for I-3(-) reduction. The bifacial DSC with obtained carbon CE achieved a high power conversion efficiency (PCE) of 5.04% under rear-side illumination, which approaches 85% that of front-side illumination (6.07%). Moreover, the device shows excellent stability as confirmed by the aging test. These promising results reveal the enormous potential of this transparent carbon CE in scaling up and commercialization of low cost and effective bifacial DSCs.

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