4.8 Article

Photopolymeric Multifunctional Dendrimer toward Holographic Applications

Journal

ACS APPLIED MATERIALS & INTERFACES
Volume 4, Issue 9, Pages 4921-4926

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/am3012406

Keywords

interference pattern; diffraction grating; dendrimer; photopolymer

Funding

  1. Brain Korea 21 Program at KAIST
  2. Korea Science and Engineering Foundation (KOSEF) (WCU Program) [31-2008-000-10055-0]

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We present a photopolymeric multifunctional dendrimer for holographic applications. In this study, we described a synthesis of multiphotoreactive dendrimer and phase compatible polymer matrix as well as a numerical simulation of the dendrimer. This holographic photopolymer containing a nanosized photoreactive organic dendrimer could address the aggregation issue of conventional inorganic nanoparticle additives and allowed writing-induced shrinkage to be successfully reduced to the extent of acceptable values for 130 mu m thick film. In this report, holographic performance including diffraction efficiency (DE), transmission, photosensitivity, modulation of refractive index, polarization sensitivity, and volume shrinkage has been discussed. The page-wise recording by using an amplitude spatial light modulator (SLM) was also demonstrated.

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