4.8 Article

Synthesis of Amphiphilic Brookite Nanoparticles with High Photocatalytic Performance for Wide Range of Application

Journal

ACS APPLIED MATERIALS & INTERFACES
Volume 4, Issue 9, Pages 4846-4852

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/am301183t

Keywords

brookite; hydrothermal method; oleic acid; amphiphilicity; photocatalyst; photoinduced hydrophilicity

Funding

  1. Ministry of Education, Culture, Sports, Science, and Technology of Japan [23750238]
  2. Grants-in-Aid for Scientific Research [23750238] Funding Source: KAKEN

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Brookite TiO2 nanoparticles with amphiphilic properties were successfully synthesized with a water-soluble titanium glycolate complex precursor using an oleate-modified hydrothermal growth process. The similar to 20-40 nm TiO2 nanoparticles were highly dispersible in both water and cyclohexane. The activity of the brookite nanoparticles for the degradation of acetaldehyde under UV irradiation was higher than that of Degussa P-25 TiO2 powder. A spin-coated brookite film prepared on a polyimide substrate exhibited photoinduced hydrophilicity. Thus, these synthesized brookite solution. nanoparticles could be applied as a photocatalytic coating

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