Journal
ACS APPLIED MATERIALS & INTERFACES
Volume 3, Issue 12, Pages 4782-4786Publisher
AMER CHEMICAL SOC
DOI: 10.1021/am201278c
Keywords
CO2 sequestration; mesoporous carbon (CMK-3); in situ polymerization; solid-supported amine sorbents; impregnation; polymer-carbon composites
Funding
- ONR MURI [00006766, N00014-09-1-1066]
- Advanced Energy Consortium
Ask authors/readers for more resources
Here we report carbon-based composites polyethylenimine-mesocarbon (PEI-CMK-3) and polyvinylamine-mesocarbon (PVA-CMK-3) that can be used to capture and rapidly release CO2. CO2 uptake by the synthesized composites was determined using a gravimetric method at 30 degrees C and 1 atm; the 39% PEI-CMK-3 composite had similar to 12 wt % CO2 uptake capacity and the 37% PVA-CMK-3 composite had similar to 13 wt % CO2 uptake capacity. A desorption temperature of 75 degrees C was sufficient for regeneration. The CO2 uptake was the same when using 10% CO2 in a 90% CH4, C2H6, and C3H8 mixture, underscoring this composite's efficacy for CO2 sequestration from natural gas.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available