4.8 Article

Friction and Adhesion of Hierarchical Carbon Nanotube Structures for Biomimetic Dry Adhesives: Multiscale Modeling

Journal

ACS APPLIED MATERIALS & INTERFACES
Volume 2, Issue 9, Pages 2570-2578

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/am100409s

Keywords

carbon nanotube; fiber; friction; adhesion; interface; gecko mimicking; dry adhesives; mechanical properties; molecular dynamics; finite element analysis

Funding

  1. NSF [CMMI-0825990]

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With unique hierarchical fibrillar structures on their feet, gecko lizards can walk on vertical walls or even ceilings. Recent experiments have shown that strong binding along the shear direction and easy lifting in the normal direction can be achieved by forming unidirectional carbon nanotube array with laterally distributed tips similar to gecko's feet. In this study, a multiscale modeling approach was developed to analyze friction and adhesion behaviors of this hierarchical fibrillar system. Vertically aligned carbon nanotube array with laterally distributed segments at the end was simulated by coarse grained molecular dynamics. The effects of the laterally distributed segments on friction and adhesion strengths were analyzed, and further adopted as cohesive laws used in finite element analysis at device scale. The results show that the laterally distributed segments play an essential role in achieving high force anisotropy between normal and shear directions in the adhesives. Finite element analysis reveals a new friction-enhanced adhesion mechanism of the carbon nanotube array, which also exists in gecko adhesive system. The multiscale modeling provides an approach to bridge the microlevel structures of the carbon nanotube array with its macrolevel adhesive behaviors, and the predictions from this modeling give an insight into the mechanisms of gecko-mimicking dry adhesives.

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