Journal
ACS APPLIED MATERIALS & INTERFACES
Volume 1, Issue 3, Pages 661-667Publisher
AMER CHEMICAL SOC
DOI: 10.1021/am800197j
Keywords
cross-linked glass; oxygen diffusion; singlet oxygen
Funding
- Danish National Research Foundation
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Oxygen diffusion coefficients, D, have been measured in poly(methyl methacrylate) (PMMA) films containing small amounts of a cinnamic acid derived cross-linker. In the technique employed, the time evolution of oxygen sorption into the film was monitored using the phosphorescence of singlet oxygen as a spectroscopic probe. Although the effect of adding up to 1 mol % of the cross-linker is clearly manifested in the molecular weight and T-g of these samples, values of D are only moderately influenced. Nevertheless, a systematic decrease in the value of D is discernible as the extent of cross-linking is increased. Although it is reasonable to expect that, in a glassy polymer, cross-linking should not significantly perturb the local motions and confined changes in free volume that influence the translational motion of a small penetrant such as oxygen, our data indicate that even small amounts of a cross-linker can, nevertheless, have a noticeable and potentially meaningful effect. Although UV irradiation of the polymer films disrupts the cinnamic acid derived cross-linker via a [2 + 2] cycloreversion reaction, the photoinduced changes observed in D appear, rather, to reflect degradation reactions in the PMMA-based polymer.
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