4.7 Article

Activating basal plane in NiFe layered double hydroxide by Mn2+ doping for efficient and durable oxygen evolution reaction

Journal

NANOSCALE HORIZONS
Volume 3, Issue 5, Pages 532-537

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c8nh00121a

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Funding

  1. National Natural Science Foundation of China
  2. Program for Changjiang Scholars and Innovative Research Team in the University [IRT1205]
  3. Fundamental Research Funds for the Central Universities
  4. Ministry of Finance of PRC
  5. National Key Research and Development Project [2016YFF0204402]
  6. Ministry of Education of PRC

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Foreign metal ions with reducing ability were doped into NiFe layered double hydroxides (NiFe-LDHs) to activate the basal plane in NiFe-LDHs for oxygen evolution reaction (OER). Mn2+-Doped NiFe-LDH array electrode yields a low onset potential of 1.41 V and exhibits outstanding stability. The study herein illustrates a new dimension of electronic structure regulation and promises further optimization of highly efficient electrocatalysts.

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