Journal
CHEM
Volume 4, Issue 2, Pages 285-297Publisher
CELL PRESS
DOI: 10.1016/j.chempr.2017.12.005
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Funding
- Australian Research Council [ARC DP170103317]
- Griffith University Postdoctoral and Research Fellowship
- Griffith University New Research Grant
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Downsizing the catalyst to atomic scale provides an effective way to maximize the atom efficiency and enhance activity for electrocatalysis. Here, we report a concept whereby graphene defects trap atomic Ni species (aNi) inside to form an integrity (aNi@defect). X-ray adsorption characterization and density-functional-theory calculation revealed that the diverse defects in graphene can induce different local electronic densities of state (DOSs) of aNi, which suggests that aNi@defect serves as an active site for unique electrocatalytic reactions. As examples, aNi@G585 is responsible for the oxygen evolution reaction (OER), and aNi@G5775 activates the hydrogen evolution reaction (HER). The derived catalyst exhibits exceptionally good activity for both HER and OER, e.g., an overpotential of 70 mV at 10 mA/cm(2) for HER (analogous to the commercial Pt/C) and 270 mV at 10 mA/cm(2) for OER (much superior to that of Ir oxide).
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