Journal
CHEMISTRYSELECT
Volume 3, Issue 16, Pages 4289-4291Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/slct.201800738
Keywords
Br center dot center dot center dot pi(Chelate) Interaction; Coordination Polymer; Copper; 16-Member Chelate Ring
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Funding
- SERB, India [SB/FT/CS-185/2012]
- DST
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A one-dimensional coordination polymer (1D CP) [Cu(nip)(4-brpy)(2)] (1) containing 16-member metal-ligand chelate ring exhibits unprecedented Br center dot center dot center dot pi(chelate) interaction. The nucleus-independent chemical shifts (NICS) calculation reveals that the chelate ring has aromaticity and strong interaction energy (-24.8 kcal/mol) which plays important role in molecular self-assembly in the crystal structure.
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