Journal
CHEMISTRYSELECT
Volume 3, Issue 2, Pages 340-347Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/slct.201702350
Keywords
photophysical studies; synthesis; 1,2,4-triazines; alpha-unsubstituted-2,2 '-bipyridines; X-ray diffraction analysis
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Funding
- Russian Science Foundation [16-43-02020]
- DST-RSF Major Research Project [INT/ RUS/RSF/P-08]
- Russian Science Foundation [16-43-02020] Funding Source: Russian Science Foundation
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An efficient approach towards -unsubstituted-2,2-bipyridines, their aza-analogs and 3,6-disubstituted-1,2,4-triazine precursors is reported via pot, atom, step economic (PASE) process starting from isonitrosoacetophenone hydrazone and readily available hetero-arylnitriles. The crystal structures of three key compounds were confirmed by means of X-ray diffraction analysis. In addition the photophysical properties of the new (aza)-2,2-pyridines were studied.
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