Journal
CHEMISTRYSELECT
Volume 3, Issue 16, Pages 4173-4178Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/slct.201800590
Keywords
alternating copolymerization; fluorinated polymer surfactant; multi-component polycondensation; peptides; Ugi's 4CC
Categories
Funding
- JSPS KAKENHI [JP15H00718, JP17H03070]
- Nagase science technology foundation
- Kanamori foundation
Ask authors/readers for more resources
Three-component polycondensation with an aldehyde, perfluoroalkylammonium triflate, and potassium isocyanoacetate produced amphiphilic fluorinated alternating peptides. The polymers work as a surfactant, which form associates in organic solvent. The thermo-dependent structures and surface activity of the associates in organic solvents were evaluated by the results of UV-vis and diffusion-ordered NMR spectral measurements at various concentrations and temperatures. It also turned out that the regularly aligned bulky substituents in the main chain stabilize the micelles kinetically formed in organic solvent.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available