Journal
CHEMISTRYSELECT
Volume 3, Issue 4, Pages 1202-1204Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/slct.201800038
Keywords
Alkenes; Alkynes; Base; Borylation; Metal-free
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Funding
- Guangdong Natural Science Foundation [2016 A030313750]
- Project of Enhancing School with Innovation of Guangdong Ocean University [GDOU2017052502]
- Zhanjiang Natural Science Foundation [A15445, A14457]
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The transition metal-free method for borylation of alkynes and alkenes with bis(pinacolato)diboron has been developed, producing the correspondent organoborons under mild reaction conditions. This reaction was an efficient, practical and environment-friendly process which brings forth vinylboronate products with excellent regioselectivity in the borylation of alkynes with bis(pinacolato)diboron, while in the meantime the diboryl alkanes were obtained using alkenes as substrates.
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