Journal
ORGANIC CHEMISTRY FRONTIERS
Volume 5, Issue 12, Pages 1896-1899Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8qo00301g
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- Soochow University
- National Natural Science Foundation of China [21722205]
- Project of Scientific and Technologic Infrastructure of Suzhou [SZS201708]
- Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
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The radical-mediated azidoheteroarylation of unactivated olefins has been accomplished for the first time based on the strategy of intramolecular distal heteroaryl migration. A variety of synthetically useful heteroaryl-substituted alkyl azides are readily furnished under mild reaction conditions. The utility of the protocol is manifested by readily converting the products to piperidine, beta-pipecolic acid, and triazole derivatives.
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