Journal
ORGANIC CHEMISTRY FRONTIERS
Volume 5, Issue 12, Pages 1962-1966Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8qo00380g
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Funding
- High End Talent Program of Yunnan Province [2015HA028]
- Natural Science Foundation of Yunnan Province [2016FA004]
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A convenient, mild and high stereoselective C-glycosylation reaction has been developed. Glycosyl acetates were coupled with terminal alkynes via ZnBr2-activation at room temperature. Their applications were further demonstrated by the straightforward synthesis of a key intermediate in the formal synthesis of (+)-varitriol.
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