Journal
ORGANIC CHEMISTRY FRONTIERS
Volume 5, Issue 14, Pages 2249-2253Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8qo00513c
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Funding
- National Natural Science Foundation [21772046]
- Program of Innovative Research Team of Huaqiao University [Z14X0047]
- Recruitment Program of Global Experts (1000 Talents Plan)
- Natural Science Foundation of Fujian Province [2016J01064]
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An environmentally benign and convenient method is developed to access a variety of functionalized geminal-diborylalkanes from various electron-deficient alkynes and B(2)pin(2). The reactions proceed via the Domino-Borylation-Protodeboronation (DBP) strategy under mild conditions with high regioselectivity, high chemoselectivity, broad functional group tolerance as well as high yields. Meanwhile, further applications of the gem-diboronate products have been explored by silver-catalyzed deboronation-difluorination, base-mediated protodeboronation as well as deborylative secondary alkylation of 2-phenylpyridine N-oxides.
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