Journal
ORGANIC CHEMISTRY FRONTIERS
Volume 5, Issue 5, Pages -Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7qo00994a
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Funding
- Tokyo Chemical Industry Foundation
- Pesticide Science Society of Japan
- JSPS [JP16H01017]
- Grants-in-Aid for Scientific Research [16H01017] Funding Source: KAKEN
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Pyridine tetrafluoro-(6)-sulfanes (SF4) with alkenyl or alkyl substituents have been synthesized for the first time via the radical addition reactions of pyridine-SF4 chlorides to alkynes or alkenes in good to high yields. X-Ray crystallographic analysis and DFT calculations disclosed an octahedral symmetrical trans-configuration of the hypervalent tetrafluorosulfanyl center. In contrast to phenyl-SF4 analogues, pyridine-SF4 compounds were found to be stable, which expands the utility of pyridine-SF4 compounds.
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