Journal
ORGANIC CHEMISTRY FRONTIERS
Volume 5, Issue 7, Pages 1113-1117Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7qo01098b
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Funding
- National Natural Science Foundation of China [21532006, 21690074]
- Chinese Academy of Sciences [QYZDJ-SSW-SLH035]
- Strategic Priority Research Program of the Chinese Academy of Sciences [XDB17020300]
- Dalian Bureau of Science and Technology [2016RD07]
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A palladium-catalyzed intramolecular asymmetric reductive amination of racemic -branched ketones bearing the poorly nucleophilic sulfonamides has been successfully developed through dynamic kinetic resolution, providing chiral -sultams with two contiguous stereogenic centers with high diastereoselectivity and enantioselectivity.
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