4.7 Article

High Performance of Supercapacitor from PEDOT:PSS Electrode and Redox Iodide Ion Electrolyte

Journal

NANOMATERIALS
Volume 8, Issue 5, Pages -

Publisher

MDPI
DOI: 10.3390/nano8050335

Keywords

PEDOT:PSS; catalysis; redox electrolyte; stability

Funding

  1. Innovation Promotion Project of Beijing Municipal Commission of Education, China [TJSHG2015 11021002]
  2. Beijing Natural Science Foundation of China [2132009, 2122015]
  3. Talents project of Beijing Organization Department [2017000020124G095]
  4. Natural Science Foundation of China (NSFC) [51063009, 51573021, 51203012, 21271031]
  5. Opening Foundation of the State Key Laboratory of Organic-Inorganic Composites [oic-201801009]

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Insufficient energy density and poor cyclic stability is still challenge for conductive polymer-based supercapacitor. Herein, high performance electrochemical system has been assembled by combining poly (3,4-ethylenedioxythiophene) (PEDOT):poly (styrene sulfonate) (PSS) redox electrode and potassium iodide redox electrolyte, which provide the maximum specific capacity of 51.3 mAh/g and the retention of specific capacity of 87.6% after 3000 cycles due to the synergic effect through a simultaneous redox reaction both in electrode and electrolyte, as well as the catalytic activity for reduction of triiodide of the PEDOT:PSS.

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