Journal
APPLICATIONS OF ENGINEERING MATERIALS, PTS 1-4
Volume 287-290, Issue -, Pages 1585-+Publisher
TRANS TECH PUBLICATIONS LTD
DOI: 10.4028/www.scientific.net/AMR.287-290.1585
Keywords
Dehydration; 5-Hydroxymethylfurfural; Ionic Liquid
Funding
- Natural Science Foundation of China [20806007]
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The preparation of 5-hydroxymethylfurfural (5-HMF) through the dehydration of fructose with room temperature ionic liquids (ILs) has received much attention as a way of producing liquid fuels from renewable resources, but the cost of the process is considerably increased with IL as a solvent rather than as a catalyst. In this work, we have shown that the alkaline Ionic Liquid, 1-Butyl-3-methylimidazolium Hydroxide ([BMIM]OH), can be used as a catalyst in the conversion of fructose to 5-HMF. The maximum yield of 5-HMF was 91.6% at 160 degrees C after 8 h using dimethylsulfoxide (DMSO) as solvent, and the ketose is more easily dehydrated than aldose in this catalyst system.
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