Journal
ADVANCED MATERIALS INTERFACES
Volume 5, Issue 17, Pages -Publisher
WILEY
DOI: 10.1002/admi.201800384
Keywords
self-healing polymers; supramolecular chemistry
Funding
- National Science Foundation (NSF) [DMR1744306]
- J. E. Sirrine Foundation Endowment at Clemson University
- EPSCoR Program under NSF [OIA-1655740]
Ask authors/readers for more resources
Recent advances of supramolecular chemistry utilized in the development of self-healing polymers have revealed that the rate and equilibrium constants of bond dissociation/re-association, bonding directionality, chain relaxation time, decay rate of chain relaxation after damage, and cluster formation may impact the healing efficiency in a given environment. This review provides an assessment of supramolecular chemistries responsible for self-healing using H-bonding, metal-ligand, host-guest, ionic, pi-pi, and hydrophobic interactions. The impact of these chemistries on self-healing is examined for various polymeric systems with multifunctional applications which are unique to supramolecular networks. This review also discusses the driving forces leading to physical damage closure in the context of supramolecular bond dynamics, providing insights into the design principles to achieve efficient recovery.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available