4.6 Article

300 nm Spectral Resolution in the Mid-Infrared with Robust, High Responsivity Flexible Colloidal Quantum Dot Devices at Room Temperature

Journal

ACS PHOTONICS
Volume 5, Issue 8, Pages 3009-3015

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsphotonics.8b00738

Keywords

midinfrared; quantum dots; flexible; air-processed; detector

Funding

  1. Royal Society of New Zealand under the Marsden Fund [E2646/3416]
  2. Rutherford Discovery Fellowship [E2675/2990]

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HgTe colloidal nanocrystals (NCs) are used as the sensitizing layer with a scalable, all air-processed patterning method to produce flexible room temperature multicolor detectors operating in the mid-infrared (MIR) spectral region. ;These devices demonstrate a color sensitivity down to 300 nm in the MIR (similar to 10% of scale), with superior responsivities for this class of device, up to 0.9 A/W, and competitive specific detectivity up to 8 x 10(9) Jones at 200 Hz and 300 K. Furthermore, these devices utilize a cheap and robust substrate material that allows operation after deformation up to 45 degrees without degradation over many cycles. As such, this offers a template for ultra low-cost MIR detectors with a performance that rivals microbolometers, but with better measurement speed and spectral sensitivity. As such, these devices showcase the advantages of using colloidal NCs in MIR applications.

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