Journal
NANO ENERGY
Volume 48, Issue -, Pages 510-517Publisher
ELSEVIER
DOI: 10.1016/j.nanoen.2018.04.001
Keywords
Covalent heterostructure; Agglomeration free; Sodium/lithium storage; High capacity
Categories
Funding
- National Natural Science Foundation of China [51774251]
- Hebei Science Foundation for Distinguished Young Scholars [B2017203313]
- Hundred Excellent Innovative Talents Support Program in Hebei Province [SLRC2017057]
- State key Project of Research and Development of China [2016YFA0200102]
- Hebei Natural Science Foundation [B2015203096]
- Scientific Research Foundation for the Returned Overseas Chinese Scholars [CG2014003002]
- State Key Laboratory of Advanced Technology for Materials Synthesis and Processing (Wuhan University of Technology) [2017-KF-14]
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The high volume expansion and serious agglomeration during sodiation/lithiation of transition metal phosphides (TMPs) raise up challenging kinetic issues and rapid capacity fading upon cycling. The good dispersion and confined movement of individual TMP particles are critical in mitigating the agglomeration, which however have been rarely concerned. In this work, we report a novel covalent heterostructure with monodisperse Ni2P immobilized on N, P-co-doped carbon nanosheets (Ni2P@NPC), which exhibits a remarkable reversible discharge capacity and outstanding long-term durability for both sodium storage (361 mA h g(-1) @100 mAg(-1) after 300 cycles, and 181 mA h g(-1) @500 mAg(-1) after 1200 cycles) and lithium storage (1555 mA h g(-1) @100 mAg(-1) after 130 cycles, and 603 mA h g(-1) @1000 mAg(-1) after 800 cycles). Most importantly, using the in-situ TEM visualized technique, we demonstrate that the immobility and monodisperse nature of Ni2P are responsible for the agglomeration-free charge storage process upon cycling. The density functional theory (DFT) calculations reveal the strong covalent coupling between Ni(2)p and NPC, which realizes the electronic structure engineering of both TMP and carbon buffer, and uncovers the origin of long-term stability and outstanding capacity.
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