Journal
NANO ENERGY
Volume 48, Issue -, Pages 500-509Publisher
ELSEVIER
DOI: 10.1016/j.nanoen.2018.04.011
Keywords
Hydrogen evolution reaction; Electrocatalytic water splitting; Metal phosphide; Metal-caged carbon matrix; Catalyst-support interaction
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Funding
- National Key R&D Program of China [2017YFA0204804]
- National Natural Science Foundation of China [21573219]
- Strategic Priority Research Program of Chinese Academy of Sciences [XDB17000000]
- China Postdoctoral Science Foundation [2016M590237]
- CNPC-DICP Joint Research Center
- Young Thousand Talents Program of China
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Developing cost-effective and stable electrocatalysts towards hydrogen evolution reaction (HER) is important for the conversion of renewable energy via electrocatalytic water splitting reaction. Herein, we present a simple and general strategy for the preparation of a series of metal (M: Fe, Co and Ni) phosphide catalysts that were anchored on metal-caged carbon matrix. In the first step, metal-grafted carbon precursors (M/M@NC) were rationally synthesized through metal-catalyzed growth process. Following phosphorization treatment transformed the metal precursors to metal phosphides (MP/M@NC) with the inheritance of the strong catalyst-support connection, which leads to efficient charge transport and prevents the detachment of the catalysts from the support. Benefitting from several structural advantages including high dispersability of active sites, good conductivity and strong interfacial interaction, the as-prepared MP/M@NC catalysts show high performance for HER in acidic solution. In particular, the FeP/Fe@NC exhibits extremely low overpotentials of -49 and -130 mV for achieving current densities of -10 and -100 mA cm(-2), respectively, and remarkable long-term durability, which highlights the importance of rational catalyst/support design towards efficient and stable electrocatalysis.
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