Journal
NANO ENERGY
Volume 45, Issue -, Pages 407-412Publisher
ELSEVIER
DOI: 10.1016/j.nanoen.2018.01.026
Keywords
Tantalum pentoxide; Nanoporous film; Oxygen deficiency; Microbattery
Categories
Funding
- National Natural Science Foundation of China [51672182, 51772197, 51422206]
- Thousand Young Talents Plan
- Jiangsu Natural Science Foundation [BK20151219, BK20140009]
- Key University Science Research Project of Jiangsu Province [17KJA430013]
- 333 High-Level Talents Project in Jiangsu Province
- Six Talent Peaks Project in Jiangsu Province
- Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
- RFBR [16-29-06439]
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Electrode architectures with large capacity and good stability are exceedingly desired but remain an intriguing challenge for energy storage applications such as on-chip integrated microbatteries, where there is a grand need for high-energy and high-power three-dimensional (3D) electrodes to replace the conventional planar electrodes. Here we report a highly efficient and durable lithium electrode based on 3D self-supported nanoporous tantalum pentoxide (Ta2O5) film. The Ta2O5 film is prepared by electrochemically anodizing tantalum metal in ammonium fluoride electrolyte and subsequent thermal annealing at 450 degrees C in argon atmosphere, which does not crystallize the film but gives rise to significant amount of oxygen deficiency. The Ta2O5 film exhibits a high lithium capacity of similar to 480 mAh g(-1) and remarkable cycling stability over 8000 cycles at a rate of 5 C, which could be attributed to improved transport kinetics and structural integrity as a result of amorphous structure, oxygen deficiency, and nanoporous architecture.
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