Journal
JOURNAL OF MATERIALS CHEMISTRY C
Volume 6, Issue 28, Pages 7568-7575Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8tc01553h
Keywords
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Funding
- National Science Center (Poland) [UMO-2017/27/B/ST5/02557]
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The recent advances in remote luminescent thermometry give promise for numerous important biomedical applications including temperature T mapping with sub-micrometer spatial resolution and real time kinetics studies within single cells. The ongoing challenge is to find luminophores, which exhibit many exorbitant parameters in a single luminescent nanoparticle, for example, high (e.g. S-R > 2% per K) temperature sensitivities in the physiological temperature range, high luminescence brightness in the NIR spectral region, simplicity and reliability of T readout and mapping. Here, we show an unprecedented approach to luminescent T sensing, which relies on highly temperature dependent non-resonant 1064 nm NIR photoexcitation and a 880 nm anti-Stokes avalanche-like NIR emission from Nd3+ doped nanoparticles. The behavior of NaYF4, Y2O3, YGdO3, YAlO3, Y3Al5O12, LiLaP4O12, Gd2O3 materials and rate-equation modeling suggest that this photon-avalanche phenomenon offers extraordinary features, such as S-R > 4% per K at 300-350 K, high brightness in the NIR region and a double mode, intensity or time-resolved based T readout.
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