4.6 Article

Broadband white-light emission with a high color rendering index in a two-dimensional organic-inorganic hybrid perovskite

Journal

JOURNAL OF MATERIALS CHEMISTRY C
Volume 6, Issue 5, Pages 1171-1175

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c7tc04868h

Keywords

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Funding

  1. NSFC [21525104, 21622108, 21601188, 91422301, 21373220, 51402296, 21571178, 51502288, 51502290]
  2. NSF for the Distinguished Young Scholars of Fujian Province [2016J06012]
  3. NSF of Fujian Province [2015J05040]
  4. Strategic Priority Research Program of the Chinese Academy of Sciences [XDB20000000]
  5. Youth Innovation Promotion of CAS [2015240, 2016274]
  6. State Key Laboratory of Luminescence and Applications [SKLA-2016-09]

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Two-dimensional (2D) organic-inorganic hybrid layered perovskites have attracted increasing attention as promising candidates in optoelectronics, due to their excellent physical attributes. However, although great efforts have been made, broadband white-light emission with a high color rendering index based on 2D hybrid perovskites still remains rare. Here, we report a broadband white-light emissive 2D organic-inorganic hybrid (110)-oriented perovskite, N-(3-aminopropyl) imidazole tetrachloro-lead (1), in which the 2D corrugated layered inorganic framework is formed by corner-shared highly distorted lead chloride octahedra. Remarkably, the color rendering index of 1 is up to 93, which is superior to that of previously reported broadband white-light emission in 2D organic-inorganic hybrid perovskites. Such a 2D hybrid layered perovskite material with a high color rendering index may provide potential applications in white light-emitting diodes.

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