Journal
JOURNAL OF MATERIALS CHEMISTRY C
Volume 6, Issue 20, Pages 5420-5426Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8tc00970h
Keywords
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Funding
- German Research Foundation [ES 361/2-1, INST 40/467-1 FUGG]
- state of Baden-Wurttemberg through bwHPC
- National Natural Science Foundation of China [51625304, 51461165301]
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Dibenzo[a, e]pentalenes (DBPs) are promising candidates to be used as ambipolar or n-type semiconductors in organic field-effect transistors (OFETs). For n-channel conduction, low LUMO energy levels are required. Furthermore, a close molecular packing in the solid state is advantageous. Here we present thioether-functionalized DBPs with LUMO energies down to -3.47 eV as well as a DBP sulfone with a LUMO energy of -3.94 eV. X-ray crystallography revealed 1-D p-stacking or herringbone packing in the solid state with close intramolecular distances between the DBP cores. Two thio-DBPs and the DBP sulfone showed n-channel conduction in FET measurements on well-aligned crystals with electron mobilities of up to 0.18 cm2 V-1 s(-1), to date the highest reported values for n-channel conduction in DBP derivatives. The short synthetic route will in the future allow for facile access to a variety of thio-and sulfone-DBPs for n-channel or ambipolar semiconduction.
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