4.6 Article

Performance comparison of fluorinated and chlorinated donor-acceptor copolymers for polymer solar cells

Journal

JOURNAL OF MATERIALS CHEMISTRY C
Volume 6, Issue 17, Pages 4658-4662

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c8tc00948a

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Funding

  1. National Natural Science Foundation of China [61366003, 11774141]
  2. Natural Science Foundation of Jiangxi Province [20171BAB216017]
  3. Science and Technology Project of the education department of Jiangxi Province, China [GJJ160723]

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Fluorinated and chlorinated donor-acceptor alternating copolymers, F-PBTQT and Cl-PBTQT, were synthesized and used as donor materials for polymer solar cells. Among them, Cl-PBTQT exhibited much better device performance, and a single-junction efficiency of 8.16% was achieved, indicating that chlorination could be a better strategy than fluorination to develop highly efficient polymer donors.

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