Journal
JOURNAL OF MATERIALS CHEMISTRY A
Volume 6, Issue 31, Pages 15095-15101Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8ta04817g
Keywords
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Funding
- FWF [Z222-N19]
- FFG within the project CO2 TRANSFER [848862]
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We report reversible electrochemical capture and release of carbon dioxide using the well-known dye precursor and industrial catalyst anthraquinone. Although quinones are well-studied for electrochemical capture and release of CO2 in solution, we have discovered that a 100 nm film of anthraquinone can realize this in a heterogeneous fashion. In-depth spectroelectrochemical studies were performed in order to study the mechanism of this CO2 capture and release. Anthraquinone films reached an uptake capacity of 5.9 mmol(CO2) g(AQ)(-1).
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