Journal
JOURNAL OF MATERIALS CHEMISTRY A
Volume 6, Issue 24, Pages 11424-11434Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8ta02287a
Keywords
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Funding
- Science Challenge Project [TZ2018004]
- National Natural Science Foundation of China [51327804]
- China Academy of Engineering Physics Research Institute [18zh0079]
- Open Project of State Key Laboratory Cultivation Base for Nonmetal Composites and Functional [14tdfk05]
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Nitro-aromatic explosives existing on the surface of the Earth are difficult to degrade, and they greatly harm the ecological environment and human security. Herein, we successfully conducted the large-scale synthesis of novel flower-like MoSe2 3D microspheres and nanospheres by a simple hydrothermal method. The two types of MoSe2 3D spheres had a high crystal quality with abundant nanosheets, and their diameters were approximately 1.5 m and 300-400 nm, respectively. The Brunauer-Emmett-Teller (BET) and UV-vis diffuse reflectance spectra (UV-vis DRS) analyses revealed that the specific surface area and the band gap of MoSe2 microspheres and nanospheres were 33.3 m(2) g(-1) and 1.68 eV and those of the nanostructures were 13.6 m(2) g(-1) and 1.52 eV, respectively. Moreover, two different morphologies of MoSe2 were used for the degradation of nitrobenzene (NB), p-nitrophenol (PNP) and 2,4-dinitrophenol (2,4-DNP) through a photocatalytic process. The results demonstrated that the three nitro-aromatic explosive solutions NB, PNP and 2,4-DNP (40 mg L-1) could be completely degraded by MoSe2 3D microspheres under visible-light irradiation in 3.5 h, 1.5 h and 2.5 h, and the degradation time for MoSe2 nanospheres was 4.5 h, 2.5 h and 4 h, respectively. The mechanism of the photocatalytic reaction was also investigated in detail, and the photocatalytic degradation process was found to follow the pseudo-first-order kinetics. Our study demonstrated the potential application of MoSe2 microspheres as a photocatalyst for the degradation of nitro-aromatic explosives and other organic contaminants.
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