Journal
JOURNAL OF MATERIALS CHEMISTRY A
Volume 6, Issue 15, Pages 6335-6343Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8ta01265b
Keywords
-
Funding
- National Natural Science Foundation of China [51572015]
- New Teachers Fund for Doctor Stations, Ministry of Education of China [20120010120004]
Ask authors/readers for more resources
The exploration of new anode materials with high gravimetric and volumetric Na-ion storage performances is urgent and advantageous, but it remains a great challenge. In this study, CoTe2/G composite nanosheets are prepared to achieve this goal by a solvothermal method due to the good properties and high density of 7.92 g cm(-3) of bulk CoTe2. In the composite, CoTe2 nanoparticles with a size of 39 nm are uniformly anchored on graphene with strong interfacial interactions. The tap density of the composite can be as high as 1.82 g cm(-3). As an anode material for SIBs, the CoTe2/G composite exhibits a high initial reversible gravimetric capacity of 382 mA h g(-1) and a volumetric capacity of 695.2 mA h cm(-3) along with excellent rate performance. Even at 1, 2 and 5 A g(-1), the CoTe2/G composite still delivers gravimetric capacities as high as 295, 272 and 246 mA h g (1) and volumetric capacities of 536.9, 495.1 and 447.7 mA h cm(-3). After 1000 cycles at 2 A g(-1), the reversible gravimetric and volumetric capacities remain at 245 mA h g(-1) and 445.9 mA h cm(-3), respectively. The electrochemical dynamic analyses indicate that the Na-ion storage behaviour in the CoTe2/G composite is a surface-controlled capacitive process, which is helpful for higher rate performance. Besides, the enhanced performance of the CoTe2/G anode is ascribed to strong interfacial interaction between CoTe2 and graphene, which can effectively improve electron transfer and alleviate the volume changes of CoTe2 during the discharge/charge processes in SIBs. Accordingly, the CoTe2/G composite has great application prospect as a promising anode candidate for smart SIBs.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available