Journal
JOURNAL OF MATERIALS CHEMISTRY A
Volume 6, Issue 6, Pages 2449-2455Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7ta09646a
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Funding
- Natural Science Foundation of China [61535003, 21403034, 61475034, 51771053]
- National Key Basic Research Program of China [2015CB352002]
- Fundamental Research Funds for the Central Universities [2242017K41007]
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The passivation of defects at perovskite grain boundaries (GB) is crucial in achieving highly efficient and stable perovskite solar cells. Unlike the widely used additive passivation method where a mixture of additives and perovskite precursor is used for preparing perovskite films, we herein developed a new defect post-healing method via dip-coating trioctylphosphine oxide (TOPO) ligands on pre-fabricated carbon-based mesoscopic perovskite solar cells (MPSCs). Since perovskites have formed before post-healing, TOPO ligands are selectively adsorbed onto the exposed perovskite surface and hence have little influence on charge extraction of interfaces. The defects are post-healed via O atoms in P=O bonds coordinated to halide-deficient sites, leading to an enhancement of the power conversion efficiency (PCE) from 11.0% to 12.8%. Moreover, due to the three hydrophobic long chain alkyls in TOPO, the humidity stability of the device has also been improved simultaneously.
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