4.6 Article

Enhanced redox activity of a hollow conjugated microporous polymer through the generation of carbonyl groups by carbonylative Sonogashira coupling

Journal

JOURNAL OF MATERIALS CHEMISTRY A
Volume 6, Issue 15, Pages 6233-6237

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c8ta01379a

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Funding

  1. Basic Science Research Program through the National Research Foundation of Korea (NRF) - Ministry of Science, ICT and Future Planning [2016R1E1A1A01941074]
  2. (R&D Convergence Program) of the National Research Council of Science & Technology (NST) of Korea [CAP-15-02-KBSI]

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Redox active 1,4-bis( 3-phenylpropynoyl) benzene moieties were incorporated into a hollow conjugated microporous polymer via carbonylative Sonogashira coupling of 1,3,5-triethynylbenzene with 1,4-diiodobenzene in the presence of carbonmonoxide. The resultant redox active material showed enhanced energy storage performance for pseudocapacitors.

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