Journal
JOURNAL OF ENERGY CHEMISTRY
Volume 30, Issue -, Pages 121-131Publisher
ELSEVIER
DOI: 10.1016/j.jechem.2018.01.015
Keywords
Biomass-derived carbon materials; Goat hair; Nitrogen; Oxygen and phosphorus tri-doping; Lithium sulfur batteries
Funding
- Sichuan Normal University [DJ GX2017017, DJ GX2017018]
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Biomass-derived carbon materials have aroused widespread concern as host material of sulfur to enhance electrochemical performances for lithium-sulfur batteries. Herein, goat hair, as a low-cost and eco-friendly precursor, is employed to fabricate cauliflower-like in-situ nitrogen, oxygen and phosphorus tri-doped porous biomass carbon (NOPC) by a facile activation with H3PO4 and carbonization process. The morphology and microstructure of NOPC can be readily tuned by altering pyrolysis temperature. The as-prepared NOPC matrix material carbonized at 600 degrees C possesses 3D hierarchical porous structure, high specific surface area (535.352 m(2) g(-1)), and appropriate pore size and pore size distribution. Encapsulating sulfur into the NOPC depends on a stem-melting technology as cathode materials of Li-S batteries. Due to the synergistic effect of special physical structure and inherent tri-doping of N, O and P, electrons and ions transfer and utilization of active sulfur in the materials are improved, and the shuttle behaviors of soluble lithium polysulfides are also mitigated. Consequently, the S/NOPC-600 composite exhibits excellent electrochemical performance, giving a high initial discharge capacity of 1185 mA h g(-1) at 0.05 C and maintaining a relatively considerable capacity of 489 mA h g(-1) at 0.2 C after 300 cycles. Our work shows that a promising candidate for cathode material of Li-S batteries can be synthesized using low-cost and renewable biomass materials by a facile process. (C) 2018 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. and Science Press. All rights reserved.
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