4.6 Article

Electrochemical engineering approach of high performance solid-state flexible supercapacitor device based on chemically synthesized VS2 nanoregime structure

Journal

JOURNAL OF ENERGY CHEMISTRY
Volume 31, Issue -, Pages 79-88

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.jechem.2018.05.011

Keywords

Chemical method; VS2; Supercapacitor; Gel electrolyte; Symmetric device

Funding

  1. [DST/TMD/MES/2k16/09]

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Portable and furnished electronics appliances demand power efficient energy storage devices where electrochemical supercapacitors gain much more attention. In this concern, a simple, low-cost and industry scalable successive ionic layer adsorption and reaction (SILAR) approach has been adopted to deposit nanostructured VS2 onto flexible and light-weight stainless steel (SS) substrate towards supercapacitor application. The nanocrystalline nature with hexagonal crystal structure has been confirmed for VS2 through structural analysis. The VS2 electrode exhibits a maximum specific capacitance of 349 F g(-1) with a super stable behavior in three-electrode liquid-state configuration. Fabricated flexible symmetric solid-state supercapacitor (FSSC) device using gel electrolyte yields specific power of 1.5 kW kg(-1) (specific energy of 25.9 Wh kg(-1)) with a widen voltage window of 1.6 V. A red LED has been glown for 30 s using the system consisted of two devices in series combination. Furthermore, the system glows a combination of 21 red LEDs network with acronym 'VNIT', demonstrating commercial exposure. The attribution of device demonstration even under mechanical stress holds great promise towards advanced flexible electronics application. (C) 2018 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. and Science Press. All rights reserved.

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