Journal
ASIAN JOURNAL OF ORGANIC CHEMISTRY
Volume 7, Issue 7, Pages 1380-1384Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ajoc.201800241
Keywords
C-H aunctionalization; hydroarylation; ruthenium; sulfoximines; water
Categories
Funding
- SERB [EMR/2014/385]
- CSIR, India
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A Ru-catalyzed intramolecular hydroarylation of arenes in an aqueous medium is presented herein. With the aid of methyl phenyl sulfoximine or an amide directing group, this atom-efficient hydroarylation of arenes ensued dihydrobenzofuran derivatives. Sequential double hydroarylation of arene motifs resulted in highly peripheral-decorated heterocycles. Deuterium labeling studies and control experiments offer valuable information in understanding the reactivity and the mechanistic data.
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