Journal
ASIAN JOURNAL OF ORGANIC CHEMISTRY
Volume 7, Issue 7, Pages 1330-1333Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ajoc.201800235
Keywords
alkynes; C-C coupling; C-H activation; rhodium; sulfur heterocycles; homogeneous catalysis
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Funding
- JSPS KAKENHI [JP16H01037, JP 17H06092]
- JST (ACT-C)
- Nagase Science Technology Foundation
- Yamada Science Foundation
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A rhodium(III)-catalyzed direct alkenylation of benzo[b]thiophenes, thieno[3,2-b]thiophene, and benzo[b]furans with diarylacetylenes proceeds effectively through regioselective C-H bond cleavage at the C2 position and syn-selective carborhodation on the triple bond.
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