Journal
ASIAN JOURNAL OF ORGANIC CHEMISTRY
Volume 7, Issue 7, Pages 1151-1163Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ajoc.201800133
Keywords
allenes; annulation; C-H activation; hydroarylation; transition metals
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Funding
- Ministry of Science and Technology of the Republic of China [MOST-105-2633-M-007-003]
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Transition-metal-catalyzed C-H functionalizations with allenes lead to unique selectivity challenges due to the presence of two adjacent carbon-carbon double bonds, which enables a series of atom- and step-economical alkenylation, allenylation, allylation, dienylation, and annulation reactions of different substrates. This Focus Review highlights the recent remarkable advancements made in transition-metal-catalyzed C-H functionalization with allenes.
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