Journal
ASIAN JOURNAL OF ORGANIC CHEMISTRY
Volume 7, Issue 5, Pages 852-864Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ajoc.201800091
Keywords
asymmetric synthesis; cyclization; heterocycles; small ring systems; ylides
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Funding
- Austrian Science Funds (FWF) [P26387-N28]
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The use of readily accessible ammonium ylides for (asymmetric) transformations, especially cyclization reactions, has received considerable attention over the past two decades. A variety of highly enantioselective protocols to facilitate annulation reactions have recently been introduced as an alternative to other common methods including S-ylide-mediated strategies. It is the intention of this short review to provide an introduction to this field by highlighting the potential of ammonium ylides for (asymmetric) cyclization reactions as well as to present the limitations and challenges of these methods.
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