4.5 Review

Recent Development of Light-Mediated Carboxylation Using CO2 as the Feedstock

Journal

ASIAN JOURNAL OF ORGANIC CHEMISTRY
Volume 7, Issue 8, Pages 1439-1447

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/ajoc.201800226

Keywords

carbocarboxylation; carbon dioxide; hydrocarboxylation; photoredox; transition metals

Funding

  1. National University of Singapore
  2. Ministry of Education (MOE) of Singapore [R-143-000-665-114, R-143-000-696-114]
  3. GSK-EDB [R-143-000-687-592]
  4. A*STAR RIE2020 AME [R-143-000-690-305]
  5. National Natural Science Foundation of China [21702142]

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CO2 is an attractive renewable C1 feedstock owing to its abundance, low cost, and nontoxicity. Developing new catalytic protocols for CO2 utilization is of great importance. With the development of photoredox catalysis over the past decades, light-driven CO2 fixation has attracted significant attention. This Review will focus on recent development of light-promoted carboxylation utilizing CO2 as a C1 source to synthesize value-added chemicals in the area of organic synthesis.

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