Journal
ASIAN JOURNAL OF ORGANIC CHEMISTRY
Volume 7, Issue 8, Pages 1642-1647Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ajoc.201800313
Keywords
aldehydes; carbocations; C-F activation; electrophilic addition; thionium cation
Categories
Funding
- Center of Excellence for Innovation in Chemistry (PERCH-CIC)
- Office of the Higher Education Commission
- Thailand Research Fund [IRN58W0005, BRG6180005]
- Swedish Research Council (VR)
- Mahidol University under the National Research Universities Program of Thailand
Ask authors/readers for more resources
Bismuth(III) trifluoromethanesulfonate [Bi(OTf)(3)] mediated mild electrophilic aromatic formylation utilizing difluoro(phenylsulfanyl)methane (PhSCF2H) as a formylating agent in hexafluoro-2-propanol (HFIP) as a recyclable ionizing solvent has been developed. The active formylating species was generated via C-F bond cleavage and was characterized to be a bis(phenylsulfanyl)methyl cation by experimental and computational H-1 and C-13 NMR.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
