4.6 Article

Co-Doped CuO Nanoarray: An Efficient Oxygen Evolution Reaction Electrocatalyst with Enhanced Activity

Journal

ACS SUSTAINABLE CHEMISTRY & ENGINEERING
Volume 6, Issue 3, Pages 2883-2887

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acssuschemeng.7b03752

Keywords

Co doping; CuO; Nanoarry; Oxygen evolution reaction; Electrocatalyst

Funding

  1. National Natural Science Foundation of China [21575137]

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It is highly desired to enhance the catalytic activity of oxygen evolution reaction (OER) electrocatalysts made of earth abundant elements. In this Letter, we report that the OER activity of a CuO nanoarray can be largely enhanced by Co doping. In 1.0 M KOH, the Co-CuO nanoarray on copper foam requires a current densities of 50 and 100 mA cm(-2) at overpotentials of only 299 and 330 mV, respectively. It also shows superior long-term durability over 15 h with a turnover frequency of 0.056 mol O-2 s(-1) at an overpotential of 300 mV.

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